| SP | Smoltz, J.Smoltz, John >> | 39 | 2006 | R | 92 | 10 | 10 | 7 | 2 | 2.75 | .266 | 1.06 | 7.3 | 2.3 | 7.0 | 75.1 | 61 | 23 | 23 | 1 | 19 | 58 | 3 | 0 | 0 | 1 | 8 | 2 | 1 | 2.47 |
| SP | Schmidt, J.Schmidt, Jason >> | 33 | 2006 | R | 88 | 8 | 8 | 4 | 1 | 3.67 | .327 | 1.37 | 8.7 | 3.7 | 6.9 | 56.1 | 54 | 23 | 23 | 3 | 23 | 43 | 0 | 0 | 0 | 0 | 4 | 5 | 1 | 3.66 |
| SP | Millwood, K.Millwood, Kevin # >> | 32 | 2006 | R | 68 | 9 | 9 | 6 | 1 | 5.58 | .314 | 1.34 | 9.2 | 3.1 | 5.5 | 59.2 | 60 | 37 | 37 | 6 | 20 | 36 | 1 | 0 | 0 | 1 | 4 | 2 | 0 | 4.22 |
| SP | Glavine, T.Glavine, Tom >> | 40 | 2006 | L | 67 | 7 | 7 | 1 | 2 | 5.05 | .353 | 1.63 | 10.3 | 4.4 | 5.5 | 41.0 | 47 | 23 | 23 | 3 | 20 | 25 | 0 | 0 | 0 | 0 | 4 | 0 | 1 | 4.20 |
| RP | Birkins, K.Birkins, Kurt >> | 26 | 2006 | L | 79 | 19 | 0 | 1 | 1 | 4.09 | .313 | 1.32 | 6.1 | 5.7 | 5.3 | 22.0 | 15 | 10 | 10 | 2 | 14 | 13 | 0 | 1 | 3 | 0 | 0 | 1 | 1 | 5.05 |
| RP | Sikorski, B.Sikorski, Brian >> | 32 | 2006 | R | 70 | 28 | 0 | 0 | 1 | 2.70 | .292 | 1.16 | 8.0 | 2.8 | 9.0 | 26.2 | 23 | 8 | 8 | 2 | 8 | 26 | 0 | 8 | 1 | 0 | 0 | 2 | 0 | 3.15 |
| RP | Villone, R.Villone, Ron >> | 36 | 2006 | L | 46 | 15 | 0 | 1 | 1 | 6.75 | .407 | 2.06 | 12.6 | 7.2 | 6.3 | 10.2 | 14 | 10 | 8 | 1 | 8 | 7 | 0 | 1 | 1 | 0 | 0 | 0 | 1 | 5.30 |
| RP | Moylan, P.Moylan, Peter >> | 28 | 2006 | R | 34 | 12 | 0 | 0 | 1 | 3.65 | .302 | 1.22 | 9.8 | 1.5 | 7.5 | 12.1 | 13 | 5 | 5 | 2 | 2 | 10 | 0 | 2 | 0 | 0 | 0 | 1 | 0 | 4.25 |