| SP | Martinez, P.Martinez, Pedro | Nationals | R | 61.0 | 16 | 16 | 8 | 6 | 3.65 | .308 | 1.30 | 8.3 | 3.5 | 9.5 | 120.2 | 111 | 49 | 49 | 13 | 46 | 127 | 6 | 0 | 0 | 0 | 11 | 4 | 1 | 3.54 |
| RP | Chapman, A.Chapman, Aroldis | Reds | L | 59.0 | 41 | 0 | 5 | 0 | 1.72 | .299 | 1.22 | 6.1 | 5.0 | 12.5 | 52.1 | 35 | 13 | 10 | 5 | 29 | 72 | 0 | 4 | 0 | 0 | 0 | 3 | 0 | 3.33 |
| SP | Scherzer, M.Scherzer, Max | Nationals | R | 55.0 | 16 | 16 | 9 | 4 | 3.91 | .287 | 1.20 | 7.4 | 3.5 | 8.4 | 96.2 | 79 | 42 | 42 | 16 | 37 | 90 | 0 | 0 | 0 | 0 | 9 | 1 | 0 | 4.48 |
| SP | Kershaw, C.Kershaw, Clayton | Dodgers | L | 54.0 | 16 | 16 | 9 | 6 | 4.22 | .297 | 1.24 | 9.2 | 2.1 | 10.8 | 108.2 | 110 | 53 | 51 | 14 | 25 | 129 | 2 | 0 | 0 | 0 | 10 | 3 | 2 | 3.07 |
| SP | Gonsolin, T.Gonsolin, Tony | Dodgers | R | 53.0 | 16 | 16 | 8 | 4 | 3.59 | .280 | 1.16 | 6.8 | 3.7 | 5.8 | 97.2 | 73 | 39 | 39 | 9 | 40 | 62 | 1 | 0 | 0 | 1 | 9 | 1 | 1 | 4.20 |