| SP | Koufax, S.Koufax, Sandy >> | 30 | 1965 | L | 97 | 10 | 10 | 7 | 2 | 3.45 | .257 | 1.02 | 7.6 | 1.7 | 7.7 | 70.1 | 59 | 31 | 27 | 9 | 13 | 60 | 3 | 0 | 0 | 0 | 7 | 1 | 2 | 3.56 |
| SP | Leonard, D.Leonard, Dutch >> | 22 | 1914 | L | 91 | 11 | 11 | 6 | 1 | 2.11 | .259 | 1.03 | 6.6 | 2.8 | 5.9 | 72.2 | 53 | 20 | 17 | 3 | 22 | 47 | 0 | 0 | 0 | 0 | 8 | 1 | 1 | 3.19 |
| SP | Mathewson, C.Mathewson, Christy >> | 28 | 1908 | R | 83 | 11 | 11 | 2 | 6 | 3.53 | .284 | 1.15 | 7.9 | 2.5 | 5.8 | 79.0 | 69 | 35 | 31 | 8 | 22 | 51 | 1 | 0 | 0 | 0 | 6 | 3 | 0 | 3.97 |
| SP | Pfiester, J.Pfiester, Jack >> | 28 | 1906 | L | 74 | 11 | 11 | 7 | 3 | 3.08 | .276 | 1.13 | 7.4 | 2.9 | 4.5 | 84.2 | 69 | 35 | 29 | 7 | 27 | 42 | 4 | 0 | 0 | 0 | 8 | 1 | 1 | 4.08 |
| SP | McDowell, S.McDowell, Sam >> | 23 | 1965 | L | 44 | 5 | 5 | 3 | 0 | 1.89 | .224 | 0.87 | 5.2 | 2.6 | 7.1 | 38.0 | 22 | 8 | 8 | 1 | 11 | 30 | 1 | 0 | 0 | 1 | 4 | 0 | 0 | 2.63 |
| CL | Kimbrel, C.Kimbrel, Craig >> | 24 | 2012 | R | 100 | 18 | 0 | 0 | 1 | 1.86 | .237 | 0.93 | 5.2 | 3.3 | 9.0 | 19.1 | 11 | 4 | 4 | 1 | 7 | 19 | 0 | 13 | 1 | 0 | 0 | 0 | 1 | 2.79 |
| RP | LaRoche, D.LaRoche, Dave >> | 28 | 1976 | L | 33 | 14 | 0 | 1 | 0 | 1.89 | .208 | 0.79 | 4.3 | 2.8 | 7.6 | 19.0 | 9 | 4 | 4 | 1 | 6 | 16 | 0 | 0 | 0 | 0 | 0 | 0 | 0 | 2.95 |
| RP | Smoltz, J.Smoltz, John >> | 36 | 2003 | R | 51 | 13 | 0 | 0 | 1 | 2.60 | .246 | 0.87 | 5.8 | 2.1 | 8.5 | 17.1 | 11 | 5 | 5 | 0 | 4 | 16 | 0 | 0 | 0 | 0 | 0 | 2 | 0 | 2.18 |
| RP | Boxberger, B.Boxberger, Brad >> | 26 | 2014 | R | 83 | 27 | 0 | 5 | 1 | 3.14 | .289 | 1.19 | 5.8 | 5.1 | 9.3 | 28.2 | 18 | 11 | 10 | 2 | 16 | 29 | 0 | 0 | 1 | 0 | 0 | 1 | 0 | 3.68 |
| RP | Valverde, J.Valverde, Jose >> | 24 | 2003 | R | 64 | 1 | 0 | 0 | 0 | 0.00 | .143 | 0.50 | 0.0 | 4.5 | 9.0 | 2.0 | 0 | 0 | 0 | 0 | 1 | 2 | 0 | 0 | 0 | 0 | 0 | 0 | 0 | 2.50 |
| SP | Coveleski, S.Coveleski, Stan >> | 28 | 1917 | R | 62 | 3 | 2 | 0 | 2 | 6.75 | .324 | 1.44 | 8.4 | 4.5 | 2.8 | 16.0 | 15 | 16 | 12 | 2 | 8 | 5 | 0 | 0 | 0 | 0 | 1 | 0 | 1 | 5.50 |