| SP | Maddux, G.Maddux, Greg >> | 29 | 1995 | R | 89 | 31 | 31 | 12 | 13 | 4.28 | .287 | 1.16 | 8.4 | 2.1 | 5.4 | 193.2 | 181 | 103 | 92 | 20 | 44 | 115 | 3 | 0 | 0 | 3 | 15 | 9 | 4 | 3.98 |
| SP | Carlton, S.Carlton, Steve >> | 28 | 1972 | L | 51 | 23 | 23 | 11 | 6 | 4.81 | .315 | 1.36 | 9.1 | 3.1 | 6.4 | 131.0 | 133 | 73 | 70 | 15 | 45 | 93 | 5 | 0 | 0 | 1 | 11 | 3 | 6 | 4.17 |
| SP | Mathewson, C.Mathewson, Christy >> | 28 | 1908 | R | 83 | 34 | 26 | 9 | 6 | 5.58 | .331 | 1.45 | 10.2 | 2.9 | 5.2 | 146.2 | 165 | 100 | 91 | 20 | 47 | 85 | 4 | 0 | 0 | 1 | 11 | 6 | 2 | 4.71 |
| CL | Darwin, D.Darwin, Danny >> | 34 | 1989 | R | 18 | 62 | 0 | 4 | 5 | 3.01 | .270 | 1.11 | 6.9 | 3.1 | 4.1 | 95.2 | 73 | 32 | 32 | 6 | 33 | 43 | 0 | 7 | 2 | 0 | 0 | 0 | 1 | 3.96 |
| RP | Smoltz, J.Smoltz, John >> | 36 | 2003 | R | 52 | 74 | 0 | 10 | 3 | 3.29 | .275 | 1.12 | 8.3 | 1.8 | 9.4 | 95.2 | 88 | 36 | 35 | 10 | 19 | 99 | 0 | 2 | 4 | 0 | 0 | 2 | 3 | 2.95 |
| RP | Messersmith, A.Messersmith, Andy >> | 23 | 1968 | R | 58 | 66 | 0 | 8 | 2 | 4.44 | .353 | 1.60 | 8.2 | 6.3 | 6.0 | 125.2 | 114 | 62 | 62 | 9 | 87 | 84 | 0 | 2 | 1 | 0 | 0 | 5 | 1 | 4.80 |
| RP | Treinen, B.Treinen, Blake >> | 30 | 2018 | R | 80 | 65 | 0 | 1 | 2 | 4.40 | .332 | 1.47 | 9.0 | 4.3 | 9.6 | 73.2 | 73 | 37 | 36 | 8 | 35 | 78 | 0 | 2 | 3 | 0 | 0 | 2 | 7 | 3.81 |
| RP | Fingers, R.Fingers, Rollie # >> | 35 | 1981 | R | 54 | 66 | 0 | 5 | 9 | 7.03 | .375 | 1.80 | 11.8 | 4.5 | 4.8 | 80.2 | 105 | 64 | 63 | 8 | 40 | 43 | 0 | 19 | 6 | 0 | 0 | 0 | 0 | 4.73 |