| SP | Koufax, S.Koufax, Sandy $ >> | 30 | 1965 | L | 98 | 32 | 32 | 12 | 13 | 4.07 | .305 | 1.30 | 8.7 | 3.0 | 8.3 | 232.0 | 225 | 112 | 105 | 24 | 77 | 214 | 7 | 0 | 0 | 2 | 17 | 3 | 5 | 3.53 |
| SP | Maddux, G.Maddux, Greg $$ >> | 29 | 1995 | R | 89 | 31 | 31 | 13 | 7 | 3.91 | .292 | 1.22 | 8.5 | 2.5 | 6.0 | 225.2 | 212 | 100 | 98 | 21 | 63 | 151 | 4 | 0 | 0 | 1 | 17 | 4 | 2 | 3.76 |
| SP | Hunter, C.Hunter, Catfish >> | 26 | 1972 | R | 81 | 31 | 31 | 9 | 18 | 6.17 | .356 | 1.64 | 11.1 | 3.7 | 5.2 | 207.0 | 255 | 153 | 142 | 32 | 85 | 119 | 1 | 0 | 0 | 0 | 10 | 4 | 5 | 5.15 |
| SP | Cicotte, E.Cicotte, Eddie >> | 33 | 1917 | R | 74 | 30 | 30 | 13 | 9 | 4.96 | .321 | 1.40 | 9.7 | 3.0 | 3.4 | 206.2 | 222 | 123 | 114 | 27 | 68 | 77 | 4 | 0 | 0 | 2 | 12 | 3 | 3 | 4.99 |
| SP | Drysdale, D.Drysdale, Don >> | 28 | 1964 | R | 59 | 29 | 29 | 14 | 11 | 6.15 | .344 | 1.55 | 10.3 | 3.7 | 5.1 | 188.2 | 216 | 134 | 129 | 23 | 77 | 107 | 4 | 0 | 0 | 0 | 9 | 4 | 4 | 4.74 |
| CL | Smoltz, J.Smoltz, John † >> | 36 | 2003 | R | 52 | 68 | 0 | 1 | 14 | 5.83 | .343 | 1.48 | 11.3 | 2.1 | 7.1 | 63.1 | 79 | 42 | 41 | 10 | 15 | 50 | 0 | 34 | 6 | 0 | 0 | 5 | 1 | 4.43 |
| RP | Percival, T.Percival, Troy >> | 26 | 1995 | R | 82 | 53 | 0 | 2 | 2 | 1.64 | .267 | 1.06 | 6.6 | 3.0 | 5.9 | 60.1 | 44 | 11 | 11 | 6 | 20 | 39 | 0 | 0 | 1 | 0 | 0 | 2 | 0 | 4.10 |
| RP | Pagan, E.Pagan, Emilio >> | 28 | 2019 | R | 76 | 35 | 0 | 2 | 1 | 3.99 | .320 | 1.38 | 9.5 | 3.1 | 7.6 | 38.1 | 40 | 17 | 17 | 4 | 13 | 32 | 0 | 1 | 1 | 0 | 0 | 1 | 3 | 3.79 |
| SP | Clemens, R.Clemens, Roger $$ >> | 24 | 1986 | R | 69 | 9 | 0 | 0 | 1 | 2.84 | .333 | 1.42 | 12.0 | 1.5 | 4.5 | 12.2 | 16 | 4 | 4 | 1 | 2 | 6 | 0 | 1 | 0 | 0 | 0 | 1 | 0 | 3.83 |