| CL | Drabowsky, M.Drabowsky, Moe † | Reds | R | 131.0 | 57 | 0 | 3 | 5 | 2.93 | .297 | 1.27 | 7.4 | 4.0 | 6.7 | 58.1 | 48 | 21 | 19 | 5 | 26 | 43 | 0 | 46 | 5 | 0 | 0 | 0 | 0 | 3.98 |
| RP | McDaniel, L.McDaniel, Lindy † # | Cardinals | R | 127.0 | 60 | 0 | 1 | 3 | 3.66 | .259 | 1.03 | 7.3 | 2.0 | 6.7 | 59.0 | 48 | 24 | 24 | 9 | 13 | 44 | 0 | 50 | 8 | 0 | 0 | 1 | 1 | 4.20 |
| SP | Marichal, J.Marichal, Juan | Giants | R | 109.0 | 35 | 35 | 18 | 13 | 4.19 | .302 | 1.29 | 8.8 | 2.8 | 5.6 | 249.0 | 243 | 122 | 116 | 28 | 78 | 156 | 9 | 0 | 0 | 1 | 21 | 2 | 5 | 4.17 |
| SP | Maloney, J.Maloney, Jim † # | Reds | R | 104.0 | 32 | 32 | 16 | 14 | 4.08 | .292 | 1.23 | 8.1 | 2.9 | 8.5 | 225.0 | 203 | 108 | 102 | 23 | 73 | 213 | 9 | 0 | 0 | 3 | 15 | 2 | 10 | 3.44 |
| SP | Stottlemyre, M.Stottlemyre, Mel | Colt 45's | R | 98.0 | 32 | 32 | 16 | 11 | 4.21 | .315 | 1.36 | 9.3 | 3.0 | 4.5 | 230.2 | 237 | 115 | 108 | 21 | 76 | 116 | 11 | 0 | 0 | 1 | 16 | 5 | 1 | 4.23 |
| SP | Koufax, S.Koufax, Sandy † | Dodgers | L | 96.0 | 31 | 31 | 13 | 10 | 3.87 | .293 | 1.23 | 8.6 | 2.6 | 8.8 | 211.2 | 201 | 100 | 91 | 20 | 60 | 207 | 7 | 0 | 0 | 1 | 16 | 2 | 3 | 3.15 |