| SP | Kershaw, C.Kershaw, Clayton | Pirates | L | 47.0 | 7 | 7 | 6 | 0 | 2.65 | .261 | 0.96 | 7.4 | 1.2 | 10.4 | 51.0 | 42 | 15 | 15 | 2 | 7 | 59 | 0 | 0 | 0 | 0 | 7 | 5 | 0 | 1.90 |
| SP | Scherzer, M.Scherzer, Max | Aces | R | 39.0 | 7 | 7 | 4 | 2 | 1.57 | .262 | 1.03 | 6.7 | 2.6 | 9.4 | 51.2 | 38 | 10 | 9 | 1 | 15 | 53 | 0 | 0 | 0 | 0 | 6 | 2 | 0 | 2.18 |
| CL | Chapman, A.Chapman, Aroldis | Alamos | L | 33.5 | 11 | 0 | 1 | 0 | 0.00 | .162 | 0.58 | 3.6 | 1.8 | 12.6 | 10.1 | 4 | 0 | 0 | 0 | 2 | 14 | 0 | 9 | 0 | 0 | 0 | 0 | 0 | 0.80 |
| RP | Doolittle, S.Doolittle, Sean | Suns | L | 30.5 | 21 | 0 | 3 | 1 | 2.48 | .250 | 1.00 | 6.5 | 2.5 | 7.8 | 29.0 | 21 | 8 | 8 | 5 | 8 | 25 | 0 | 3 | 0 | 0 | 0 | 0 | 0 | 4.34 |
| SP | Bumgarner, M.Bumgarner, Madison | Alamos | L | 27.0 | 6 | 6 | 4 | 1 | 3.69 | .304 | 1.31 | 8.3 | 3.5 | 11.5 | 39.0 | 36 | 16 | 16 | 4 | 15 | 50 | 0 | 0 | 0 | 0 | 4 | 0 | 0 | 2.92 |
| CL | Benoit, J.Benoit, Joaquin | Pirates | R | 26.5 | 14 | 0 | 1 | 1 | 3.86 | .311 | 1.29 | 10.3 | 1.3 | 10.9 | 14.0 | 16 | 6 | 6 | 0 | 2 | 17 | 0 | 9 | 1 | 0 | 0 | 1 | 0 | 1.21 |