| SP | Drysdale, D.Drysdale, Don † | Expos | R | 178.0 | 37 | 37 | 21 | 10 | 2.94 | .283 | 1.17 | 7.9 | 2.6 | 4.4 | 282.0 | 248 | 109 | 92 | 22 | 83 | 137 | 13 | 0 | 0 | 5 | 27 | 3 | 7 | 3.96 |
| SP | Koufax, S.Koufax, Sandy † | Dodgers | L | 176.0 | 36 | 36 | 22 | 7 | 3.17 | .268 | 1.09 | 6.9 | 2.9 | 7.9 | 255.1 | 195 | 93 | 90 | 21 | 83 | 224 | 9 | 0 | 0 | 2 | 24 | 2 | 8 | 3.31 |
| SP | McDowell, S.McDowell, Sam † | Corn Pickers | L | 118.0 | 34 | 31 | 17 | 11 | 3.20 | .303 | 1.31 | 7.0 | 4.8 | 7.5 | 208.1 | 162 | 78 | 74 | 10 | 110 | 173 | 0 | 0 | 0 | 0 | 21 | 0 | 8 | 3.55 |
| SP | Marichal, J.Marichal, Juan | Corn Pickers | R | 109.0 | 38 | 38 | 17 | 17 | 4.15 | .290 | 1.22 | 9.1 | 1.9 | 4.9 | 288.1 | 291 | 137 | 133 | 28 | 61 | 157 | 17 | 0 | 0 | 1 | 21 | 2 | 3 | 3.83 |
| RP | Abernathy, T.Abernathy, Ted | Gorillas | R | 104.0 | 85 | 0 | 9 | 3 | 2.93 | .303 | 1.29 | 7.1 | 4.5 | 5.3 | 126.0 | 100 | 47 | 41 | 10 | 63 | 74 | 0 | 14 | 5 | 0 | 0 | 1 | 2 | 4.38 |